Consider a quantum-mechanical particle of mass m moving in a potential well,
V(x)={0,∞,−a<x<a elsewhere
(a) Verify that the set of normalised energy eigenfunctions are
ψn(x)=a1sin(2anπ(x+a)),n=1,2,…
and evaluate the corresponding energy eigenvalues En.
(b) At time t=0 the wavefunction for the particle is only nonzero in the positive half of the well,
ψ(x)={a2sin(aπx),0,0<x<a elsewhere
Evaluate the expectation value of the energy, first using
⟨E⟩=∫−aaψHψdx
and secondly using
⟨E⟩=n∑∣an∣2En,
where the an are the expansion coefficients in
ψ(x)=n∑anψn(x)
Hence, show that
1=21+π28p=0∑∞[(2p+1)2−4]2(2p+1)2