Paper 3, Section II, D

Quantum Mechanics
Part IB, 2015

Define the angular momentum operators L^i\hat{L}_{i} for a particle in three dimensions in terms of the position and momentum operators x^i\hat{x}_{i} and p^i=ixi\hat{p}_{i}=-i \hbar \frac{\partial}{\partial x_{i}}. Write down an expression for [L^i,L^j]\left[\hat{L}_{i}, \hat{L}_{j}\right] and use this to show that [L^2,L^i]=0\left[\hat{L}^{2}, \hat{L}_{i}\right]=0 where L^2=L^x2+L^y2+L^z2\hat{L}^{2}=\hat{L}_{x}^{2}+\hat{L}_{y}^{2}+\hat{L}_{z}^{2}. What is the significance of these two commutation relations?

Let ψ(x,y,z)\psi(x, y, z) be both an eigenstate of L^z\hat{L}_{z} with eigenvalue zero and an eigenstate of L^2\hat{L}^{2} with eigenvalue 2l(l+1)\hbar^{2} l(l+1). Show that (L^x+iL^y)ψ\left(\hat{L}_{x}+i \hat{L}_{y}\right) \psi is also an eigenstate of both L^z\hat{L}_{z} and L^2\hat{L}^{2} and determine the corresponding eigenvalues.

Find real constants AA and BB such that

ϕ(x,y,z)=(Az2+By2r2)er,r2=x2+y2+z2,\phi(x, y, z)=\left(A z^{2}+B y^{2}-r^{2}\right) e^{-r}, \quad r^{2}=x^{2}+y^{2}+z^{2},

is an eigenfunction of L^z\hat{L}_{z} with eigenvalue zero and an eigenfunction of L^2\hat{L}^{2} with an eigenvalue which you should determine. [Hint: You might like to show that L^if(r)=0.]\left.\hat{L}_{i} f(r)=0 .\right]