Paper 2, Section II, B

Quantum Mechanics
Part IB, 2019

Let x,y,zx, y, z be Cartesian coordinates in R3\mathbb{R}^{3}. The angular momentum operators satisfy the commutation relation

[Lx,Ly]=iLz\left[L_{x}, L_{y}\right]=i \hbar L_{z}

and its cyclic permutations. Define the total angular momentum operator L2\mathbf{L}^{2} and show that [Lz,L2]=0\left[L_{z}, \mathbf{L}^{2}\right]=0. Write down the explicit form of LzL_{z}.

Show that a function of the form (x+iy)mznf(r)(x+i y)^{m} z^{n} f(r), where r2=x2+y2+z2r^{2}=x^{2}+y^{2}+z^{2}, is an eigenfunction of LzL_{z} and find the eigenvalue. State the analogous result for (xiy)mznf(r)(x-i y)^{m} z^{n} f(r).

There is an energy level for a particle in a certain spherically symmetric potential well that is 6-fold degenerate. A basis for the (unnormalized) energy eigenstates is of the form

(x21)f(r),(y21)f(r),(z21)f(r),xyf(r),xzf(r),yzf(r)\left(x^{2}-1\right) f(r),\left(y^{2}-1\right) f(r),\left(z^{2}-1\right) f(r), x y f(r), x z f(r), y z f(r) \text {. }

Find a new basis that consists of simultaneous eigenstates of LzL_{z} and L2\mathbf{L}^{2} and identify their eigenvalues.

[You may quote the range of LzL_{z} eigenvalues associated with a particular eigenvalue of L2\mathbf{L}^{2}.]