B2.22

Applications of Quantum Mechanics
Part II, 2001

A particle of charge ee moves freely within a cubical box of side aa. Its initial wavefunction is

(2/a)32sin(πx/a)sin(πy/a)sin(πz/a).(2 / a)^{-\frac{3}{2}} \sin (\pi x / a) \sin (\pi y / a) \sin (\pi z / a) .

A uniform electric field E\mathcal{E} in the xx direction is switched on for a time TT. Derive from first principles the probability, correct to order E2\mathcal{E}^{2}, that after the field has been switched off the wave function will be found to be

(2/a)32sin(2πx/a)sin(πy/a)sin(πz/a).(2 / a)^{-\frac{3}{2}} \sin (2 \pi x / a) \sin (\pi y / a) \sin (\pi z / a) .