B4.24

Applications of Quantum Mechanics
Part II, 2001

Derive the Bloch form of the wave function ψ(x)\psi(x) of an electron moving in a onedimensional crystal lattice.

The potential in such an NN-atom lattice is modelled by

V(x)=n(2U2mδ(xnL))V(x)=\sum_{n}\left(-\frac{\hbar^{2} U}{2 m} \delta(x-n L)\right)

Assuming that ψ(x)\psi(x) is continuous across each lattice site, and applying periodic boundary conditions, derive an equation for the allowed electron energy levels. Show that for suitable values of ULU L they have a band structure, and calculate the number of levels in each band when UL>2U L>2. Verify that when UL1U L \gg 1 the levels are very close to those corresponding to a solitary atom.

Describe briefly how the band structure in a real 3-dimensional crystal differs from that of this simple model.