B4.24
Part II, 2001
Derive the Bloch form of the wave function of an electron moving in a onedimensional crystal lattice.
The potential in such an -atom lattice is modelled by
Assuming that is continuous across each lattice site, and applying periodic boundary conditions, derive an equation for the allowed electron energy levels. Show that for suitable values of they have a band structure, and calculate the number of levels in each band when . Verify that when the levels are very close to those corresponding to a solitary atom.
Describe briefly how the band structure in a real 3-dimensional crystal differs from that of this simple model.