B4.24
Atoms of mass in an infinite one-dimensional periodic array, with interatomic spacing , have perturbed positions , for integer . The potential between neighbouring atoms is
for positive constant . Write down the Lagrangian for the variables . Find the frequency of a normal mode of wavenumber . Define the Brillouin zone and explain why may be restricted to lie within it.
Assume now that the array is periodically-identified, so that there are effectively only atoms in the array and the atomic displacements satisfy the periodic boundary conditions . Determine the allowed values of within the Brillouin zone. Show, for allowed wavenumbers and , that
By writing as
where the sum is over allowed values of , find the Lagrangian for the variables , and hence the Hamiltonian as a function of and the conjugate momenta . Show that the Hamiltonian operator of the quantum theory can be written in the form
where is a constant and are harmonic oscillator annihilation and creation operators. What is the physical interpretation of and ? How does this show that phonons have quantized energies?