3.II.34D
Part II, 2006
What is meant by the chemical potential of a thermodynamic system? Derive the Gibbs distribution with variable particle number , for a system at temperature and chemical potential . (You may assume that the volume does not vary.)
Consider a non-interacting gas of fermions in a box of fixed volume, at temperature and chemical potential . Use the Gibbs distribution to find the mean occupation number of a one-particle quantum state of energy . Assuming that the density of states is , for some constant , deduce that the mean number of particles with energies between and is
Why can be identified with the Fermi energy when ? Estimate the number of particles with energies greater than when is small but non-zero.