3.II.34D

Statistical Physics
Part II, 2006

What is meant by the chemical potential of a thermodynamic system? Derive the Gibbs distribution with variable particle number NN, for a system at temperature TT and chemical potential μ\mu. (You may assume that the volume does not vary.)

Consider a non-interacting gas of fermions in a box of fixed volume, at temperature TT and chemical potential μ\mu. Use the Gibbs distribution to find the mean occupation number of a one-particle quantum state of energy ε\varepsilon. Assuming that the density of states is Cε1/2C \varepsilon^{1 / 2}, for some constant CC, deduce that the mean number of particles with energies between ε\varepsilon and ε+dε\varepsilon+d \varepsilon is

Cε12dεe(εμ)/T+1.\frac{C \varepsilon^{\frac{1}{2}} d \varepsilon}{e^{(\varepsilon-\mu) / T}+1} .

Why can μ\mu be identified with the Fermi energy εF\varepsilon_{F} when T=0T=0 ? Estimate the number of particles with energies greater than εF\varepsilon_{F} when TT is small but non-zero.