3.II.32D

Principles of Quantum Mechanics
Part II, 2007

Let

x^=(2mω)1/2(a+a),p^=(mω2)1/2i(aa)\hat{x}=\left(\frac{\hbar}{2 m \omega}\right)^{1 / 2}\left(a+a^{\dagger}\right), \quad \hat{p}=\left(\frac{\hbar m \omega}{2}\right)^{1 / 2} i\left(a^{\dagger}-a\right)

be the position and momentum operators for a one-dimensional harmonic oscillator of mass mm and frequency ω\omega. Write down the commutation relations obeyed by aa and aa^{\dagger} and give an expression for the oscillator Hamiltonian H(x^,p^)H(\hat{x}, \hat{p}) in terms of them. Prove that the only energies allowed are En=ω(n+12)E_{n}=\hbar \omega\left(n+\frac{1}{2}\right) with n=0,1,2,n=0,1,2, \ldots and give, without proof, a formula for a general normalised eigenstate n|n\rangle in terms of 0|0\rangle.

A three-dimensional oscillator with charge is subjected to a weak electric field so that its total Hamiltonian is

H1+H2+H3+λmω2(x^1x^2+x^2x^3+x^3x^1)H_{1}+H_{2}+H_{3}+\lambda m \omega^{2}\left(\hat{x}_{1} \hat{x}_{2}+\hat{x}_{2} \hat{x}_{3}+\hat{x}_{3} \hat{x}_{1}\right)

where Hi=H(x^i,p^i)H_{i}=H\left(\hat{x}_{i}, \hat{p}_{i}\right) for i=1,2,3i=1,2,3 and λ\lambda is a small, dimensionless parameter. Express the general eigenstate for the Hamiltonian with λ=0\lambda=0 in terms of one-dimensional oscillator states, and give the corresponding energy eigenvalue. Use perturbation theory to compute the changes in energies of states in the lowest two levels when λ0\lambda \neq 0, working to the leading order at which non-vanishing corrections occur.