4.II.33A

Applications of Quantum Mechanics
Part II, 2007

Consider a 1-dimensional chain of 2N2 N atoms of mass mm (with NN large and with periodic boundary conditions). The interactions between neighbouring atoms are modelled by springs with alternating spring constants KK and GG, with K>GK>G.

In equilibrium, the separation of the atoms is aa, the natural length of the springs.

Find the frequencies of the longitudinal modes of vibration for this system, and show that they are labelled by a wavenumber qq that is restricted to a Brillouin zone. Identify the acoustic and optical bands of the vibration spectrum, and determine approximations for the frequencies near the centre of the Brillouin zone. What is the frequency gap between the acoustic and optical bands at the zone boundary?

Describe briefly the properties of the phonons in this system.