Show that the concentration C(x,t) of a diffusible chemical substance in a stationary medium satisfies the partial differential equation
∂t∂C=∇⋅(D∇C)+F
where D is the diffusivity and F(x,t) is the rate of supply of the chemical.
A finite amount of the chemical, 4πM, is supplied at the origin at time t=0, and spreads out in a spherically symmetric manner, so that C=C(r,t) for r>0,t>0, where r is the radial coordinate. The diffusivity is given by D=kC, for constant k. Show, by dimensional analysis or otherwise, that it is appropriate to seek a similarity solution in which
C=(kt)βMαf(ξ),ξ=(Mkt)γr and ∫0∞ξ2f(ξ)dξ=1
where α,β,γ are constants to be determined, and derive the ordinary differential equation satisfied by f(ξ).
Solve this ordinary differential equation, subject to appropriate boundary conditions, and deduce that the chemical occupies a finite spherical region of radius
r0(t)=(75Mkt)1/5
[Note: in spherical polar coordinates
∇C≡(∂r∂C,0,0) and ∇⋅(V(r,t),0,0)≡r21∂r∂(r2V)⋅]