4.II.32D

Principles of Quantum Mechanics
Part II, 2008

Define the interaction picture for a quantum mechanical system with Schrödinger picture Hamiltonian H0+V(t)H_{0}+V(t) and explain why either picture gives the same physical predictions. Derive an equation of motion for interaction picture states and use this to show that the probability of a transition from a state n|n\rangle at time zero to a state m|m\rangle at time tt is

P(t)=120tei(EmEn)t/mV(t)ndt2P(t)=\frac{1}{\hbar^{2}}\left|\int_{0}^{t} e^{i\left(E_{m}-E_{n}\right) t^{\prime} / \hbar}\left\langle m\left|V\left(t^{\prime}\right)\right| n\right\rangle d t^{\prime}\right|^{2}

correct to second order in VV, where the initial and final states are orthogonal eigenstates of H0H_{0} with eigenvalues EnE_{n} and EmE_{m}.

Consider a perturbed harmonic oscillator:

H0=ω(aa+12),V(t)=λ(aeiνt+aeiνt)H_{0}=\hbar \omega\left(a^{\dagger} a+\frac{1}{2}\right), \quad V(t)=\hbar \lambda\left(a e^{i \nu t}+a^{\dagger} e^{-i \nu t}\right)

with aa and aa^{\dagger} annihilation and creation operators (all usual properties may be assumed). Working to order λ2\lambda^{2}, find the probability for a transition from an initial state with En=ω(n+12)E_{n}=\hbar \omega\left(n+\frac{1}{2}\right) to a final state with Em=ω(m+12)E_{m}=\hbar \omega\left(m+\frac{1}{2}\right) after time tt.

Suppose tt becomes large and perturbation theory still applies. Explain why the rate P(t)/tP(t) / t for each allowed transition is sharply peaked, as a function of ν\nu, around ν=ω\nu=\omega.