3.II.33E

Applications of Quantum Mechanics
Part II, 2008

Consider the body-centred cuboidal lattice LL with lattice points (n1a,n2a,n3b)\left(n_{1} a, n_{2} a, n_{3} b\right) and ((n1+12)a,(n2+12)a,(n3+12)b)\left(\left(n_{1}+\frac{1}{2}\right) a,\left(n_{2}+\frac{1}{2}\right) a,\left(n_{3}+\frac{1}{2}\right) b\right), where aa and bb are positive and n1,n2n_{1}, n_{2} and n3n_{3} take all possible integer values. Find the reciprocal lattice L~\widetilde{L}and describe its geometrical form. Calculate the volumes of the unit cells of the lattices LL and L~\widetilde{L}.

Find the reciprocal lattice vector associated with the lattice planes parallel to the plane containing the points (0,0,b),(0,a,b),(12a,12a,12b),(a,0,0)(0,0, b),(0, a, b),\left(\frac{1}{2} a, \frac{1}{2} a, \frac{1}{2} b\right),(a, 0,0) and (a,a,0)(a, a, 0). Deduce the allowed Bragg scattering angles of X-rays off these planes, assuming that b=43ab=\frac{4}{3} a and that the X-rays have wavelength λ=12a\lambda=\frac{1}{2} a.