Prove that energy fluctuations in a canonical distribution are given by
⟨(E−⟨E⟩)2⟩=kBT2CV
where T is the absolute temperature, CV=∂T∂⟨E⟩∣∣∣∣V is the heat capacity at constant volume, and kB is Boltzmann's constant.
Prove the following relation in a similar manner:
⟨(E−⟨E⟩)3⟩=kB2[T4∂T∂CV∣∣∣∣∣V+2T3CV]
Show that, for an ideal gas of N monatomic molecules where ⟨E⟩=23NkBT, these equations can be reduced to
⟨E⟩21⟨(E−⟨E⟩)2⟩=3N2 and ⟨E⟩31⟨(E−⟨E⟩)3⟩=9N28