Paper 3, Section II, E

Applications of Quantum Mechanics
Part II, 2011

An electron of mass mm moves in a DD-dimensional periodic potential that satisfies the periodicity condition

V(r+l)=V(r)lΛ,V(\boldsymbol{r}+\boldsymbol{l})=V(\boldsymbol{r}) \quad \forall l \in \Lambda,

where Λ\Lambda is a D-dimensional Bravais lattice. State Bloch's theorem for the energy eigenfunctions of the electron.

For a one-dimensional potential V(x)V(x) such that V(x+a)=V(x)V(x+a)=V(x), give a full account of how the "nearly free electron model" leads to a band structure for the energy levels.

Explain briefly the idea of a Fermi surface and its rôle in explaining the existence of conductors and insulators.