Paper 3, Section II, C

Statistical Physics
Part II, 2012

A ferromagnet has magnetization order parameter mm and is at temperature TT. The free energy is given by

F(T;m)=F0(T)+a2(TTc)m2+b4m4F(T ; m)=F_{0}(T)+\frac{a}{2}\left(T-T_{c}\right) m^{2}+\frac{b}{4} m^{4}

where a,ba, b and TcT_{c} are positive constants. Find the equilibrium value of the magnetization at both high and low temperatures.

Evaluate the free energy of the ground state as a function of temperature. Hence compute the entropy and heat capacity. Determine the jump in the heat capacity and identify the order of the phase transition.

After imposing a background magnetic field BB, the free energy becomes

F(T;m)=F0(T)+Bm+a2(TTc)m2+b4m4F(T ; m)=F_{0}(T)+B m+\frac{a}{2}\left(T-T_{c}\right) m^{2}+\frac{b}{4} m^{4}

Explain graphically why the system undergoes a first-order phase transition at low temperatures as BB changes sign.

The spinodal point occurs when the meta-stable vacuum ceases to exist. Determine the temperature TT of the spinodal point as a function of Tc,a,bT_{c}, a, b and BB.