(i) Briefly describe the microcanonical ensemble.
(ii) For quantum mechanical systems the energy levels are discrete. Explain why we can write the probability distribution in this case as
p({ni})={ const >00 for E⩽E({ni})<E+ΔE otherwise
What assumption do we make for the energy interval ΔE ?
Consider N independent linear harmonic oscillators of equal frequency ω. Their total energy is given by
E({ni})=i=1∑Nℏω(ni+21)=Mℏω+2Nℏω with M=i=1∑Nni
Here ni=0,1,2,… is the excitation number of oscillator i.
(iii) Show that, for fixed N and M, the number gN(M) of possibilities to distribute the M excitations over N oscillators (i.e. the number of different choices {ni} consistent with M ) is given by
gN(M)=M!(N−1)!(M+N−1)!
[Hint: You may wish to consider the set of N oscillators plus M−1 "additional" excitations and what it means to choose M objects from this set.]
(iv) Using the probability distribution of part (ii), calculate the probability distribution p(E1) for the "first" oscillator as a function of its energy E1=n1ℏω+21ℏω.
(v) If ΔE=ℏω≪E then exactly one value of M will correspond to a total energy inside the interval (E,E+ΔE). In this case, show that
p(E1)≈gN(M)gN−1(M−n1).
Approximate this result in the limit N≫1,M≫n1.