Paper 2, Section II, E

Statistical Physics
Part II, 2014

Briefly describe the microcanonical, canonical and grand canonical ensembles. Why do they agree in the thermodynamic limit?

A harmonic oscillator in one spatial dimension has Hamiltonian

H=p22m+m2ω2x2H=\frac{p^{2}}{2 m}+\frac{m}{2} \omega^{2} x^{2}

Here pp and xx are the momentum and position of the oscillator, mm is its mass and ω\omega its frequency. The harmonic oscillator is placed in contact with a heat bath at temperature TT. What is the relevant ensemble?

Treating the harmonic oscillator classically, compute the mean energy E\langle E\rangle, the energy fluctuation ΔE2\Delta E^{2} and the heat capacity CC.

Treating the harmonic oscillator quantum mechanically, compute the mean energy E\langle E\rangle, the energy fluctuation ΔE2\Delta E^{2} and the heat capacity CC.

In what limit of temperature do the classical and quantum results agree? Explain why they differ away from this limit. Describe an experiment for which this difference has implications.