Paper 3, Section II, A

Applications of Quantum Mechanics
Part II, 2015

A particle of mass mm and energy E=2κ2/2m<0E=-\hbar^{2} \kappa^{2} / 2 m<0 moves in one dimension subject to a periodic potential

V(x)=2λm=δ(xa) with λ>0.V(x)=-\frac{\hbar^{2} \lambda}{m} \sum_{\ell=-\infty}^{\infty} \delta(x-\ell a) \quad \text { with } \quad \lambda>0 .

Determine the corresponding Floquet matrix M\mathcal{M}. [You may assume without proof that for the Schrödinger equation with potential αδ(x)\alpha \delta(x) the wavefunction ψ(x)\psi(x) is continuous at x=0x=0 and satisfies ψ(0+)ψ(0)=(2mα/2)ψ(0).]\left.\psi^{\prime}(0+)-\psi^{\prime}(0-)=\left(2 m \alpha / \hbar^{2}\right) \psi(0) .\right]

Explain briefly, with reference to Bloch's theorem, how restrictions on the energy of a Bloch state can be derived from M\mathcal{M}. Deduce that for the potential V(x)V(x) above, κ\kappa is confined to a range whose boundary values are determined by

tanh(κa2)=κλ and coth(κa2)=κλ.\tanh \left(\frac{\kappa a}{2}\right)=\frac{\kappa}{\lambda} \quad \text { and } \quad \operatorname{coth}\left(\frac{\kappa a}{2}\right)=\frac{\kappa}{\lambda} .

Sketch the left-hand and right-hand sides of each of these equations as functions of y=κa/2y=\kappa a / 2. Hence show that there is exactly one allowed band of negative energies with either (i) EE<0E_{-} \leqslant E<0 or (ii) EEE+<0E_{-} \leqslant E \leqslant E_{+}<0 and determine the values of λa\lambda a for which each of these cases arise. [You should not attempt to evaluate the constants E±.E_{\pm} .]

Comment briefly on the limit aa \rightarrow \infty with λ\lambda fixed.