A particle of mass m and energy E=−ℏ2κ2/2m<0 moves in one dimension subject to a periodic potential
V(x)=−mℏ2λℓ=−∞∑∞δ(x−ℓa) with λ>0.
Determine the corresponding Floquet matrix M. [You may assume without proof that for the Schrödinger equation with potential αδ(x) the wavefunction ψ(x) is continuous at x=0 and satisfies ψ′(0+)−ψ′(0−)=(2mα/ℏ2)ψ(0).]
Explain briefly, with reference to Bloch's theorem, how restrictions on the energy of a Bloch state can be derived from M. Deduce that for the potential V(x) above, κ is confined to a range whose boundary values are determined by
tanh(2κa)=λκ and coth(2κa)=λκ.
Sketch the left-hand and right-hand sides of each of these equations as functions of y=κa/2. Hence show that there is exactly one allowed band of negative energies with either (i) E−⩽E<0 or (ii) E−⩽E⩽E+<0 and determine the values of λa for which each of these cases arise. [You should not attempt to evaluate the constants E±.]
Comment briefly on the limit a→∞ with λ fixed.