Paper 4, Section II, A

Principles of Quantum Mechanics
Part II, 2016

(a) Consider a quantum system with Hamiltonian H=H0+VH=H_{0}+V, where H0H_{0} is independent of time. Define the interaction picture corresponding to this Hamiltonian and derive an expression for the time derivative of an operator in the interaction picture, assuming it is independent of time in the Schrödinger picture.

(b) The Pauli matrices σ=(σ1,σ2,σ3)\boldsymbol{\sigma}=\left(\sigma_{1}, \sigma_{2}, \sigma_{3}\right) satisfy

σiσj=δij+iϵijkσk\sigma_{i} \sigma_{j}=\delta_{i j}+i \epsilon_{i j k} \sigma_{k}

Explain briefly how these properties allow σ\sigma to be used to describe a quantum system with spin 12\frac{1}{2}.

(c) A particle with spin 12\frac{1}{2} has position and momentum operators x^=(x^1,x^2,x^3)\hat{\mathbf{x}}=\left(\hat{x}_{1}, \hat{x}_{2}, \hat{x}_{3}\right) and p^=(p^1,p^2,p^3)\hat{\mathbf{p}}=\left(\hat{p}_{1}, \hat{p}_{2}, \hat{p}_{3}\right). The unitary operator corresponding to a rotation through an angle θ\theta about an axis n\mathbf{n} is U=exp(iθnJ/)U=\exp (-i \theta \mathbf{n} \cdot \mathbf{J} / \hbar) where J\mathbf{J} is the total angular momentum. Check this statement by considering the effect of an infinitesimal rotation on x^,p^\hat{\mathbf{x}}, \hat{\mathbf{p}} and σ\boldsymbol{\sigma}.

(d) Suppose that the particle in part (c) has Hamiltonian H=H0+VH=H_{0}+V with

H0=12mp^2+αLσ and V=Bσ3H_{0}=\frac{1}{2 m} \hat{\mathbf{p}}^{2}+\alpha \mathbf{L} \cdot \boldsymbol{\sigma} \quad \text { and } \quad V=B \sigma_{3}

where L\mathbf{L} is the orbital angular momentum and α,B\alpha, B are constants. Show that all components of J\mathbf{J} are independent of time in the interaction picture. Is this true in the Heisenberg picture?

[You may quote commutation relations of L\mathbf{L} with x^\hat{\mathbf{x}} and p^\hat{\mathbf{p}}.]