Paper 3, Section II, A

Applications of Quantum Mechanics
Part II, 2016

(a) A spinless charged particle moves in an electromagnetic field defined by vector and scalar potentials A(x,t)\mathbf{A}(\mathbf{x}, t) and ϕ(x,t)\phi(\mathbf{x}, t). The wavefunction ψ(x,t)\psi(\mathbf{x}, t) for the particle satisfies the time-dependent Schrödinger equation with Hamiltonian

H^0=12m(i+eA)(i+eA)eϕ.\hat{H}_{0}=\frac{1}{2 m}(-i \hbar \boldsymbol{\nabla}+e \mathbf{A}) \cdot(-i \hbar \boldsymbol{\nabla}+e \mathbf{A})-e \phi .

Consider a gauge transformation

AA~=A+f,ϕϕ~=ϕft,ψψ~=exp(ief)ψ\mathbf{A} \rightarrow \tilde{\mathbf{A}}=\mathbf{A}+\nabla f, \quad \phi \rightarrow \tilde{\phi}=\phi-\frac{\partial f}{\partial t}, \quad \psi \rightarrow \tilde{\psi}=\exp \left(-\frac{i e f}{\hbar}\right) \psi

for some function f(x,t)f(\mathbf{x}, t). Define covariant derivatives with respect to space and time, and show that ψ~\tilde{\psi} satisfies the Schrödinger equation with potentials A~\tilde{\mathbf{A}} and ϕ~\tilde{\phi}.

(b) Suppose that in part (a) the magnetic field has the form B=×A=(0,0,B)\mathbf{B}=\boldsymbol{\nabla} \times \mathbf{A}=(0,0, B), where BB is a constant, and that ϕ=0\phi=0. Find a suitable A\mathbf{A} with Ay=Az=0A_{y}=A_{z}=0 and determine the energy levels of the Hamiltonian H^0\hat{H}_{0} when the zz-component of the momentum of the particle is zero. Suppose in addition that the particle is constrained to lie in a rectangular region of area A\mathcal{A} in the (x,y)(x, y)-plane. By imposing periodic boundary conditions in the xx-direction, estimate the degeneracy of each energy level. [You may use without proof results for a quantum harmonic oscillator, provided they are clearly stated.]

(c) An electron is a charged particle of spin 12\frac{1}{2} with a two-component wavefunction ψ(x,t)\psi(\mathbf{x}, t) governed by the Hamiltonian

H^=H^0I2+e2mBσ\hat{H}=\hat{H}_{0} \mathbb{I}_{2}+\frac{e \hbar}{2 m} \mathbf{B} \cdot \boldsymbol{\sigma}

where I2\mathbb{I}_{2} is the 2×22 \times 2 unit matrix and σ=(σ1,σ2,σ3)\sigma=\left(\sigma_{1}, \sigma_{2}, \sigma_{3}\right) denotes the Pauli matrices. Find the energy levels for an electron in the constant magnetic field defined in part (b), assuming as before that the zz-component of the momentum of the particle is zero.

Consider NN such electrons confined to the rectangular region defined in part (b). Ignoring interactions between the electrons, show that the ground state energy of this system vanishes for NN less than some integer NmaxN_{\max } which you should determine. Find the ground state energy for N=(2p+1)NmaxN=(2 p+1) N_{\max }, where pp is a positive integer.