Paper 2, Section II, B

Applications of Quantum Mechanics
Part II, 2019

Give an account of the variational principle for establishing an upper bound on the ground state energy of a Hamiltonian HH.

A particle of mass mm moves in one dimension and experiences the potential V=AxnV=A|x|^{n} with nn an integer. Use a variational argument to prove the virial theorem,

2T0=nV02\langle T\rangle_{0}=n\langle V\rangle_{0}

where 0\langle\cdot\rangle_{0} denotes the expectation value in the true ground state. Deduce that there is no normalisable ground state for n3n \leqslant-3.

For the case n=1n=1, use the ansatz ψ(x)eα2x2\psi(x) \propto e^{-\alpha^{2} x^{2}} to find an estimate for the energy of the ground state.