Paper 1, Section II, B

Principles of Quantum Mechanics
Part II, 2021

(a) A group GG of transformations acts on a quantum system. Briefly explain why the Born rule implies that these transformations may be represented by operators U(g):HHU(g): \mathcal{H} \rightarrow \mathcal{H} obeying

U(g)U(g)=1HU(g1)U(g2)=eiϕ(g1,g2)U(g1g2)\begin{aligned} U(g)^{\dagger} U(g) &=1_{\mathcal{H}} \\ U\left(g_{1}\right) U\left(g_{2}\right) &=e^{i \phi\left(g_{1}, g_{2}\right)} U\left(g_{1} \cdot g_{2}\right) \end{aligned}

for all g1,g2Gg_{1}, g_{2} \in G, where ϕ(g1,g2)R\phi\left(g_{1}, g_{2}\right) \in \mathbb{R}.

What additional property does U(g)U(g) have when GG is a group of symmetries of the Hamiltonian? Show that symmetries correspond to conserved quantities.

(b) The Coulomb Hamiltonian describing the gross structure of the hydrogen atom is invariant under time reversal, ttt \mapsto-t. Suppose we try to represent time reversal by a unitary operator TT obeying U(t)T=TU(t)U(t) T=T U(-t), where U(t)U(t) is the time-evolution operator. Show that this would imply that hydrogen has no stable ground state.

An operator A:HHA: \mathcal{H} \rightarrow \mathcal{H} is antilinear if

A(aα+bβ)=aˉAα+bˉAβA(a|\alpha\rangle+b|\beta\rangle)=\bar{a} A|\alpha\rangle+\bar{b} A|\beta\rangle

for all α,βH|\alpha\rangle,|\beta\rangle \in \mathcal{H} and all a,bCa, b \in \mathbb{C}, and antiunitary if, in addition,

βα=βα,\left\langle\beta^{\prime} \mid \alpha^{\prime}\right\rangle=\overline{\langle\beta \mid \alpha\rangle},

where α=Aα\left|\alpha^{\prime}\right\rangle=A|\alpha\rangle and β=Aβ\left|\beta^{\prime}\right\rangle=A|\beta\rangle. Show that if time reversal is instead represented by an antiunitary operator then the above instability of hydrogen is avoided.